Scientific Journal of KubSAU

It has been experimentally proven that thermal radiation of optically transparent solid objects forms from the entire heated volume within the spectral frequency that is allowed to pass through

Specially formed mixtures of isotopes of chemical elements have better consumer properties than their natural counterparts. Therefore, the development of methods for increasing the efficiency of the known methods for producing of isotope materials is relevant. It is known that the chemical bond is formed only in the singlet state of the spins of valence electrons of the reagents. On the basis of the known representations about dispersion of spin projections on the coordinate axes and the molecular-kinetic theory of gases was obtained an expression for the constant of the chemical reaction between the radicals occurring in the magnetic field. This expression allows calculating the reactivity of the isotopic modifications of radicals. Plasma allows to transfer many of the compounds in the gas phase. It is known that a significant part of particles in low temperature plasma is in a radical form. The equations of chemical kinetics for describing the process of oxidation of the carbon isotopes in argon-oxygen plasma occurring in an external permanent magnetic field were written in the work. It was shown that the efficiency of plasma process of isotopes separation can be increased only under insufficient oxygen relative to the stoichiometric value. These equations of chemical kinetics of processes occurring in the plasma process of incomplete oxidation of carbon isotopes needed to find experimental conditions that provide the maximum isotope effect in a magnetic field

The analysis of the various conditions of the two (four) laser radiation streams coherent addition was realized. It is shown that it is possible to create devices providing continuous subtraction of waves. In such radiation stream a continuous subtraction on the line can be replaced by the continuous addition on the photomultiplier by using a dispersive delay line. The research results can be used for creation of modern open atmospheric connection lines

Chemical processes are often connected with use or formation of condensed dispersed phase (CDP). Dispersed particles can change mobility of charges, as well as other parameters of the low-temperature plasma. The aim of this work is to study the effect of magnetic field on the processes of dispersed particles formation in argon-oxygen plasma containing iron and carbon atoms at atmospheric pressure. The equilibrium composition of iron and carbon atoms containing mixture simulated at temperatures of 1000-5000K for optimization of the plasma-forming gas composition. It is shown that in case of oxygen excess, the CDP particles contain only iron oxides. The literature data about the phase transition processes in a low-temperature plasma, as well as the data about the processes with participation of ferromagnetic particles in a constant magnetic field analyzed. The results of investigations of the dispersed particles forming in argon-oxygen plasma of arc discharge in the presence and in the absence of the magnetic field are shown. The formed disperse phase was deposited on the substrates and studied by the electron microscopy and X-ray methods. It was found that with the lack of oxygen the size of the iron-oxide particles created in the arc discharge containing iron and carbon is affected by magnetic field: in a magnetic field of 10 mT the particles are larger than in its absence

It is known that transmission coefficient of quartz glass containing the same amount of 28Si and 30Si in the silicon optical fiber is lesser than in commercial LEDs for telecommunications. Therefore it is topical to develop the method of optical glass formation with specified isotope composition in the core and in the shell. The article provides an analysis of physical and chemical processes occurring at the formation of quartz optical fiber blanks by vapor deposition from the gas phase. It is shown that the part of the silicon tetrachloride oxidation stages passes through the radical processes. Therefore for quartz glass formation with specified isotope composition it is possible to use the paramagnetic phenomena caused by the external magnetic field in a high-temperature flow at the quartz glass chemical deposition from the vapor phase. In this case alloy additive using is not necessary. Alloy additives can form density inhomogeneities in the glass. Simultaneous silicon glass formation and silicon isotope separation process bring to significant reduction of the fiber cost in comparison with isotope-enriched materials using. The permanent magnets can be used for magnetic field formation at existing process units

The steady increase in demand for isotopes requires the development of methods to increase the efficiency of isotope separation technologies. Methods of isotope separation based on thermodynamic differences of isotopic forms of the molecules don't require significant investment, but characterized by a low rate of exchange. It's known that the magnetic effect leads to a change the vibrational frequency of the molecules, and therefore their thermodynamic parameters. The change increases the thermodynamic parameters, including the exchange rate. The results of the experimental determination of the thermal effect of dissolving the salts of NaCl, KCl, CuSO4, sodium amalgam decomposition by distillate in a magnetic field and without field were shown. Magnetic interference can have a significant effect on the amalgam exchange method which was shown by quantum and mechanical analysis of the results