Scientific Journal of KubSAU

Polythematic online scientific journal
of Kuban State Agrarian University
ISSN 1990-4665
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Name

Gornyaeva Yulia Alexandrovna

Scholastic degree

—

Academic rank

—

Honorary rank

—

Organization, job position

Kuban State University
   

Web site url

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Email

semper.inmotu@yandex.ru


Articles count: 1

258 kb

PERSPECTIVE MODIFIERS FOR ANIONEXCHANGE MEMBRANES BASED ON POLYMERS WITH QUATERNARY NITROGEN ATOMS, WHICH INCLUDED IN FIVE- AND SIX-MEMBERED HETEROCYCLIC RINGS

abstract 1231609085 issue 123 pp. 1256 – 1267 30.11.2016 ru 768
The present work describes the chemical synthesis of poly-N,N-diallyl pyrrolidinium bromide and polyN,N-diallyl morpholinium bromide - high-molecular compounds containing quaternary nitrogen atoms, which included in two five- and/or six-membered heterocyclic rings. These polymers are perspective modifiers for industrially produced anion-exchange membranes, the use of which should significantly improve the resistance to degradation of the membranes at over-limiting current regimes. The structure of obtained polymers was characterized by FTIR, 1H and 13C NMR spectroscopy. The optimal reaction conditions, which increase the yield of desired products, were defined. It is shown that is preferable to use 1-butanol as a solvent and benzoyl peroxide as an initiator
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