Scientific Journal of KubSAU

Article is devoted to the numerical analysis of regional problems for system of the equations of Nernst-Plank-Puasson (NPP), to application of these regional problems to modeling and studying of mass transfer in the channel desalting of electro dialysis device. Various mathematical models of the transfer of ions in potential static mode in the form of system of the quasilinear equations with private derivatives are offered. The basic rules of occurrence and development of a spatial charge in the channel desalting of electro dialysis device are revealed

The article presents ways to estimate the socio-economic condition of the subjects of the Russian Federation using fuzzy production systems, discriminant analysis and neural networks. This study is based on the thirteen indicators of the socio-economic condition of the regions of the Russian Federation identified by RIA Rating rating agency. The goal of the work is to develop a software package combining the estimation methods above and allowing to get three alternative estimation options for a subject of the Russian Federation, using these thirteen indicators. The developed program assigns each region an estimation from the following set: AAA– the highest socio-economic condition, AA - very high, A– high, BBB– above average, BB– average, B– below average, CCC– low, CC– very low, C– the lowest indicators of the socio-economic conditions in the region of the Russian Federation. The software package is developed in Matlab and has an intuitive interface. The results can be used as an alternative to current methods of estimation of the socio-economic indicators

This article is a continuation of [1, 2] and is devoted to the description of a program complex "Region-Credit" for the assessment of financial stability, economic development, credit, socio-economic status and investment attractiveness of Russian regions. The article is an example of a comprehensive credit analysis, socio-economic status and investment attractiveness of Krasnodar Region for the period from 2008 to 2014 with the help of a program complex "Region-Credit", whose results are compared with peer review rating agency AK&M

This work presents a new approach to the countries’ credit rating definition, based on the advanced mathematical models, such as neural network model, multiple regression, cluster analysis and discriminant analysis. A range of the analyses such as discriminant, cluster, multiple regression models and a neural network were performed on the following economic figures: GDP per capita, GDP value, annual growth rate of GDP, FDI - foreign investment, rate of unemployment, consumer price inflation index, the size of government debt in percentage of GDP. The results, obtained for each model were combined in the countries’ credit rating estimation system called "7M"

In this article authors propose the asymptotic solution of the boundary value problem modeling the transport of salt ions in the cell electrodialysis desalination unit. The domain of the camera desalting broken into two subdomains: electroneutrality and space charge. Subdomains has own asymptotic expansion. The subdomain of the space charge has unique solvability of the current approach used by the solvability condition of the next approximation

This article is devoted to the asymptotic analysis of boundary value problem for a system of equations of Nernst-Planck and Poisson for a singularly perturbed system of ordinary differential equations [1], based on two parameters. This boundary value problem simulates electrodiffusion of four kinds of ions at the same time in the diffusion layer in electro-membrane systems with perfectly selective membrane, taling into consideration the reaction of recombination of two ions. Meanwhile the other two ions represent ions of a binary salt. As a simple example, we consider the transport of ions sodium, chlorine, hydrogen and hydroxide, moreover, hydrogen and hydroxyl ions recombine in the diffusion layer. A more complex case is the transfer of the products of dissociation of the dihydrogen phosphate of sodium, namely, ions of sodium and dihydrogen phosphate, the latter dissociate at the interface, in turn, hydrogen ions and hydrogen phosphate. Thus, in the solution can simultaneously store three different types of ions: sodium, hydrogen, phosphate. During the transfer, hydrogen ions and ions of hydrogen phosphate recombine to produce phosphoric acid. The article has revealed the structure of the Nernst diffusion layer at currents above Harkatsa current. It is shown, that in the diffusion layer, there are two types of boundary layers: the inner (reaction) boundary layer and boundary layer at the interface solution / membrane

The influence of dissociation / recombination of water molecules is important for understanding electroconvection processes, as some authors believe that the emergence of new carriers + H and − OH , and can lead to a reduction in the space-charge and, consequently, to electroconvection disappearance. However, as shown in [5], the dissociation of water molecules, although it reduces the space charge and increases the threshold fall potential jump at which begins electroconvection, yet it persists and effectively mixes the solution. This article is devoted to mathematical modeling of electrodiffusion of four types of ions at the same time (two salt ions as well as + H and − OH ions) in the diffusion layer in electromembrane systems with perfectly selective membrane under the joint influence of violation of electrical neutrality, and the reaction of dissociation / recombination of water molecules, development of mathematical models of these processes, building efficient algorithms asymptotic and numerical analysis for different types of electrolytes. The work proposes a new mathematical model of the process of transfer of salt ions in view of the space charge and the dissociation / recombination of water in the form of a boundary value problem for a system of ordinary differential equations. This system is reduced to a form convenient for numerical solution. We have calculated the required additional boundary conditions for the electric field. Numerical and asymptotic solution of the boundary value problem and physico-chemical analysis of the influence of dissociation / recombination on the transfer of salt ions is expected to devote the next part of the work

This article is a continuation of the previous works of the authors [The influence of reaction dissociation / recombination of molecules of water on transportation of electrolyte 1:1 in the membrane systems in the diffusion layer. Part 1. Mathematical model // Scientific journal of Kuban State Agrarian University, 2016. No. 07(121) and The influence of the reaction of dissociation / recombination of molecules of water on transportation of electrolyte 1: 1 in membrane systems in the diffusion layer. Part 2. Asymptotic analysis // Scientific journal of Kuban State Agrarian University, 2016. – №08(122)] and devoted to assessing the possibility of gravitational convection due to the recombination of hydrogen and hydroxyl ions. The article presents the solution of a boundary-value problem, which is a mathematical model of electrodiffusion for the four types of ions at the same time (two ions of salts and hydrogen and hydroxyl ions) in the diffusion layer in electro-membrane systems with ideal selective membrane, with the heat transfer equation and the Navier-Stokes equation. The article shows the possibility of the emergence of gravitational convection due to the exothermic reaction of recombination of water molecules in the depth of the solution. The article considered the reaction of recombination of hydrogen ions and hydroxyl, although the main results can be applied, after appropriate modifications, and to amfolit-containing solutions, such as wine, juices, dairy products, microbiological processing of biomass (amino acids, anions of polybasic carboxylic acids), municipal effluent (anions of phosphoric acid), etc.

This article analyzes the boundary problem model of transport of binary electrolyte membrane systems in the approximation of Ohm's law. Different methods of solution are proposed

This article describes a mathematical model of transport of salt ions in a cell with a rotating disk cation exchange membrane at transcendent current regimes, taking into account electroconvection. Based on this model, we had a theoretically study of the process of transfer of salt ions and the dependence of the thickness of the diffusion layer from the fall of potential. This article is a continuation of [8] and [9], it conducted a numerical analysis of boundary value problem for a system of equations Nernst-Planck-Poisson and Navier-Stokes equations, modeling the transport of salt ions in a cylindrical cell with a rotating disc cation exchange membrane based on electroconvection. It is shown there is an electroconvection vortex in the center of the membrane disc. The solution flows around this vortex and forms a stagnation zone in front of it. With the increase in the size of the fall of potential, the electroconvective vortex decreases and at some value, the electroconvective vortex disappears. The study was conducted in the 1000 s when the angular velocity of 30 turns in a minute and change of the potential difference of 0.2V to 1.4V with a step 0.1. As a result, in this study it is shown that the thickness of the diffusion layer is practically linearly dependent on the fall of potential. The linear dependence of the thickness of diffusion layer from the fall of potential, in the first approximation, is disturbed by a slight deflection curve, the causes of which are needed to be found by means of extra experiments