Name
Alpatova Natalia Vladimirovna
Scholastic degree
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Academic rank
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Honorary rank
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Organization, job position
Kuban State University
Web site url
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Articles count: 2
The results of study of bipolar membrane – analogue
of MB-2, modified with chemically introduced chromium
(III), iron (III) and nickel (II) hydroxides by the
method of frequency spectrum of electrochemical impedance,
by infrared spectroscopy and scanning electron
microscopy in combination with X-ray spectrum
analysis are presented. It is shown, that sequential
treatment of cation-exchanger, contained in cationexchange
membrane, with metal salt solution and alkali
solution does not result in formation of complex
compounds of these metals with ionic groups of ion
exchanger. It was found that in these conditions the
presence of heavy metals in the phase of cationexchanger
confirmed by X-ray analysis, however,
crystals of hydroxides of heavy metals are not detected
in the size range of 1000 nm to 20 nm. These heavy
metal compounds are thermally unstable and their
catalytic activity in the reaction of dissociation of water
molecules decreases with increasing temperature
during heat treatment. The introduction of low-soluble
hydroxides of d-metals (chromium (III), iron (III),
nickel(II)) by chemical method can significantly improve
the electrochemical characteristics of a bipolar
membrane. The most effective catalysts in water dissociation
reaction are the hydroxides of chromium (III)
and iron (III) and, as a consequence, membranes with
these hydroxides have a lower value of overpotential
compared with original membrane at the same current
density
In the article the mathematical model of the space charge region in the bipolar membrane is considered. The structure of the space charge region under passing of electric current, and without electric current is discussed. The results of experimental studies of water dissociation in the bipolar membrane in the presence of chromium(III) are discussed