The results of investigation of melanoidin’s formation
early stages in acidic ethanolic D-glucose – p-toluidine
model system are presented. Based on the elemental
analysis, IR- and UV-spectroscopy data obtained we
have shown, that in system studied Amadori
rearrangement product undergo the aryl amine
elimination during browning to form a nonnitrogenous
reductons with antioxidative activity in
processes of linoleic acid oxidation. It is also noted,
that in system studied inhibition of carbohydrate’s
destruction occurs because of non-reactive O-ethylglycosides
formation. The data obtained may be useful
for technology of carbohydrate-containing raw
material
In this article, we discuss the relationship between the
previously obtained model for calculating atomic radii
with electrodynamics, the hydrodynamic model of the
planets of the Solar System, and the R-function of the
structural organization of electronic systems. It is
shown that the curve of the dependence of the value
of the correction coefficient e
x
on the atomic number
of the element in form coincides with the dependence
of the ionization energy on the mass of the atom and
the R-function on the nuclear charge. The concept of
the "atomic nucleus potential", which takes into
account the energy of the nucleus and the charge of
the nucleus of the atom, is introduced. It is shown that
the radius of an atom is the product of the nuclear
potential by a factor kx
, taking into account the
characteristics of electronic levels; the energy of the
nuclear reaction is the work of the forces of the field
(potential) of the atomic nucleus along the
displacement of the atomic charge. The dependence of
the potential of the nucleus on the charge number in
the Mendeleev’s Periodic Table is shown. It is shown
that any system of satellites (or atomic shells) has a
constant ratio of its Kepler number to the mass of the
central body around which they rotate. It is shown that
in the Table of Mendeleev's chemical elements and in
the solar system, the fundamental value is the mass of
the center (the nucleus of the atom or the center of the
orbit). The ratio of the Kepler number to the mass of
the central body is a constant, within the accuracy of
construction and calculations
Studying natural phenomena in all their diversity,
humanity worked experienced in every field of
science the model of perceiving the world and
methods of obtaining information. The development
of science currently cannot be imagined without
research on the intersection of its regions. This
article presents the results of the automated systemcognitive
analysis of the size of atoms from the
main characteristics that are of research at the
interface of General chemistry elements and
intelligent systems. Dependence of nuclear radius,
mass and of the atom and the charge number are
identical in shape and size, which is probably
connected with the linear increase of these
parameters in the Periodic system of chemical
elements. There is also a similar form of the
dependences of radii of atoms from the factors ex
and x, because these factors are interrelated. The
obtained results of the ask analysis have confirmed
the theoretical assumptions and the formulae of the
dependence of main characteristics of the atom
The new benzimidazole-functionalized graphene
material based on graphene oxide (GO) and 3,3',4,4'-
tetraaminodiphenyl oxide (TADPO) was obtained
under one-step hydrothermal synthesis conditions.
According to IR spectroscopy and elemental analysis,
as a result of the reaction, benzimidazole (BI) rings are
formed, and the mass content of nitrogen is 12.3%.
The new graphene material is characterized by
excellent electrochemical efficiency in a threeelectrode
supercapacitor. As a result of the redox
activity of BI cycles the specific capacitance reaches
286 F/g at the scan rate of 2 mV/s, which is
substantially higher than the reduced graphene oxide
(RGO) sample obtained under similar conditions
without using TADPO (159 F/g at 2 mV/s)
The change in the Kepler’s atomic number in the
Periodic Table of Mendeleev is studied. It is shown
that its values decrease regularly with increasing
nuclear charge. An alternative formula for computing
the values of the Kepler’s atomic number is proposed.
It is shown that the ratio of the atomic number of
Kepler’s to the mass of the atom is a constant for each
period. The values of these constants are calculated