Scientific Journal of KubSAU

Polythematic online scientific journal
of Kuban State Agrarian University
ISSN 1990-4665
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239 kb

STUDY OF EARLY STAGES OF MELANOIDIN’S FORMATION PROCESSES IN MODEL ETHANOLIC D-GLUCOSE – pTOLUIDINE SYSTEM

abstract 1321708057 issue 132 pp. 720 – 727 31.10.2017 ru 530
The results of investigation of melanoidin’s formation early stages in acidic ethanolic D-glucose – p-toluidine model system are presented. Based on the elemental analysis, IR- and UV-spectroscopy data obtained we have shown, that in system studied Amadori rearrangement product undergo the aryl amine elimination during browning to form a nonnitrogenous reductons with antioxidative activity in processes of linoleic acid oxidation. It is also noted, that in system studied inhibition of carbohydrate’s destruction occurs because of non-reactive O-ethylglycosides formation. The data obtained may be useful for technology of carbohydrate-containing raw material
753 kb

INTERRELATION OF THE MODEL OF CALCULATIONS OF ATOMIC RADIUS AND VARIOUS SYSTEM CHARACTERISTICS

abstract 1331709031 issue 133 pp. 379 – 401 30.11.2017 ru 455
In this article, we discuss the relationship between the previously obtained model for calculating atomic radii with electrodynamics, the hydrodynamic model of the planets of the Solar System, and the R-function of the structural organization of electronic systems. It is shown that the curve of the dependence of the value of the correction coefficient e x on the atomic number of the element in form coincides with the dependence of the ionization energy on the mass of the atom and the R-function on the nuclear charge. The concept of the "atomic nucleus potential", which takes into account the energy of the nucleus and the charge of the nucleus of the atom, is introduced. It is shown that the radius of an atom is the product of the nuclear potential by a factor kx , taking into account the characteristics of electronic levels; the energy of the nuclear reaction is the work of the forces of the field (potential) of the atomic nucleus along the displacement of the atomic charge. The dependence of the potential of the nucleus on the charge number in the Mendeleev’s Periodic Table is shown. It is shown that any system of satellites (or atomic shells) has a constant ratio of its Kepler number to the mass of the central body around which they rotate. It is shown that in the Table of Mendeleev's chemical elements and in the solar system, the fundamental value is the mass of the center (the nucleus of the atom or the center of the orbit). The ratio of the Kepler number to the mass of the central body is a constant, within the accuracy of construction and calculations
7278 kb

ASC-ANALYSIS OF THE DEPENDENCE OF THE SIZES OF ATOMS OF CHEMICAL ELEMENTS ON THEIR MAIN CHARACTERISTICS

abstract 1341710055 issue 134 pp. 685 – 710 29.12.2017 ru 627
Studying natural phenomena in all their diversity, humanity worked experienced in every field of science the model of perceiving the world and methods of obtaining information. The development of science currently cannot be imagined without research on the intersection of its regions. This article presents the results of the automated systemcognitive analysis of the size of atoms from the main characteristics that are of research at the interface of General chemistry elements and intelligent systems. Dependence of nuclear radius, mass and of the atom and the charge number are identical in shape and size, which is probably connected with the linear increase of these parameters in the Periodic system of chemical elements. There is also a similar form of the dependences of radii of atoms from the factors ex and x, because these factors are interrelated. The obtained results of the ask analysis have confirmed the theoretical assumptions and the formulae of the dependence of main characteristics of the atom
230 kb

PREPARATION OF GRAPHENE MATERIAL WITH BENZIMIDAZOLE FRAGMENTS

abstract 1341710056 issue 134 pp. 711 – 719 29.12.2017 ru 664
The new benzimidazole-functionalized graphene material based on graphene oxide (GO) and 3,3',4,4'- tetraaminodiphenyl oxide (TADPO) was obtained under one-step hydrothermal synthesis conditions. According to IR spectroscopy and elemental analysis, as a result of the reaction, benzimidazole (BI) rings are formed, and the mass content of nitrogen is 12.3%. The new graphene material is characterized by excellent electrochemical efficiency in a threeelectrode supercapacitor. As a result of the redox activity of BI cycles the specific capacitance reaches 286 F/g at the scan rate of 2 mV/s, which is substantially higher than the reduced graphene oxide (RGO) sample obtained under similar conditions without using TADPO (159 F/g at 2 mV/s)
245 kb

KEPLER'S NUMBERS IN THE MODEL OF THE RUTHERFORD-BOHR

abstract 1341710081 issue 134 pp. 995 – 1005 29.12.2017 ru 653
The change in the Kepler’s atomic number in the Periodic Table of Mendeleev is studied. It is shown that its values decrease regularly with increasing nuclear charge. An alternative formula for computing the values of the Kepler’s atomic number is proposed. It is shown that the ratio of the atomic number of Kepler’s to the mass of the atom is a constant for each period. The values of these constants are calculated
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