Name
Kulagina Ludmila Georgievna
Scholastic degree
•
Academic rank
associated professor
Honorary rank
—
Organization, job position
Kazan State Power-Engineering University
Web site url
—
Articles count: 2
By the method of the dipole moments the connections of (p-XC6H4)3As=N-C6H4-Y series have been examined. The method of the vector-statistical analysis of the dipole moments helped to define the ranges and directions of the moments of (Сар)3As=N-Cар, (Сар)3As=N и N-Cар series. There has been shown that the substitution of the para-assistants X and Y in aromatic groups doesn't lead to an additional interaction influencing the electronic properties of the (Сар)3As=N-Cар group. The comparative analysis of the (Сар)3Э=N-Cар (Э=P, As) group moments specifies the essencial shift of the electron density to Сар(N) when replacing atom P to As
By the method of dipole moments, there has been determined that the tri-coordinated arsenic derivatives (p-XC6H4AsN-R)2 with R= Bu-t in the liquor exist in a cis-form, as for R=С6Н4Х-p the trans-structure is being realized. As for tetra-coordinated derivatives [XC6H4As(S)NBu-t]2 the trans-form is also beeing observed. For ortho-substituted connections, the angles of flat surfaces rotation of benzene rings have been defined