Name
Melnikov Stanislav Sergeevich
Scholastic degree
•
Academic rank
—
Honorary rank
—
Organization, job position
Kuban State University
Web site url
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Articles count: 3
The article presents the experimental results of the
study of the concentration dependence of the electrical
conductivity of heterogeneous ion-exchange
membranes that are in contact with solutions of weak
electrolytes - carboxylic acids. It is shown that in this
case the membrane conductivity is higher than the
conductivity of the solution, wherein the conductivity
of cation exchange membranes substantially greater
(by an order of magnitude) than the conductivity of
anion exchange membranes. This fact must be
considered when designing the actual electrodialysis
processes of processing solutions containing organic
ions. The work identified the need to develop modern
ideas about transport and the structural organization of
ion-exchange materials, to describe the structure of the
ion-exchange membranes that are in contact with weak
electrolytes solutions
The article illustrates the results of the research dedicated to finding a method of combining two polymeric materials - ion-exchange membranes having different chemical nature. It shows a method of applying a homogenous film MF 4SK on the surface of the heterogeneous membrane substrate to produce a chemically and mechanically stable asymmetric bipolar membrane. We have selected membrane substrate ensuring the best electrochemical performance
The current-voltage characteristics and the number of
effective ion transfer, as well as the frequency
spectrum of the electrochemical impedance of
multilayer ion-exchange membranes in a stable and
controllable thickness of the diffusion layer were
measured, using the of rotating membrane disk
complex. The article presents a comparative analysis
of the frequency spectra of the electrochemical
impedance of the source and a surface-modified
monopolar anion exchange membranes in 0.01 M
sodium chloride was made. The process of water
molecules dissociation at current densities above the
limiting one in 0.01 M sodium chloride solution was
studied in detail