Name
Bespalov Alexander Valerievich
Scholastic degree
•
Academic rank
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Honorary rank
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Organization, job position
Kuban State University
Web site url
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Articles count: 1
The present work describes the chemical synthesis of
poly-N,N-diallyl pyrrolidinium bromide and polyN,N-diallyl
morpholinium bromide - high-molecular
compounds containing quaternary nitrogen atoms,
which included in two five- and/or six-membered
heterocyclic rings. These polymers are perspective
modifiers for industrially produced anion-exchange
membranes, the use of which should significantly
improve the resistance to degradation of the
membranes at over-limiting current regimes. The
structure of obtained polymers was characterized by
FTIR, 1H and 13C NMR spectroscopy. The optimal
reaction conditions, which increase the yield of desired
products, were defined. It is shown that is preferable to
use 1-butanol as a solvent and benzoyl peroxide as an
initiator