Scientific Journal of KubSAU

Polythematic online scientific journal
of Kuban State Agrarian University
ISSN 1990-4665
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Name

Mamchuev Adra Magometovich

Scholastic degree


Academic rank

associated professor

Honorary rank

—

Organization, job position

Karachay-Cherkessia State University. WJ. Aliyev
   

Web site url

—

Email

mamchuev2007@mail.ru


Articles count: 1

381 kb

THE TRANSFER OF SALT IONS IN AN ELECTROCHEMICAL CELL WITH ROTATING MEMBRANE DISK WITH ELECTROCONVECTION. PART 3. DEPENDENCE OF THE THICKNESS FROM THE FALL OF POTENTIAL

abstract 1171603015 issue 117 pp. 272 – 283 31.03.2016 ru 681
This article describes a mathematical model of transport of salt ions in a cell with a rotating disk cation exchange membrane at transcendent current regimes, taking into account electroconvection. Based on this model, we had a theoretically study of the process of transfer of salt ions and the dependence of the thickness of the diffusion layer from the fall of potential. This article is a continuation of [8] and [9], it conducted a numerical analysis of boundary value problem for a system of equations Nernst-Planck-Poisson and Navier-Stokes equations, modeling the transport of salt ions in a cylindrical cell with a rotating disc cation exchange membrane based on electroconvection. It is shown there is an electroconvection vortex in the center of the membrane disc. The solution flows around this vortex and forms a stagnation zone in front of it. With the increase in the size of the fall of potential, the electroconvective vortex decreases and at some value, the electroconvective vortex disappears. The study was conducted in the 1000 s when the angular velocity of 30 turns in a minute and change of the potential difference of 0.2V to 1.4V with a step 0.1. As a result, in this study it is shown that the thickness of the diffusion layer is practically linearly dependent on the fall of potential. The linear dependence of the thickness of diffusion layer from the fall of potential, in the first approximation, is disturbed by a slight deflection curve, the causes of which are needed to be found by means of extra experiments
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