Name
Kovalenko Anna Vladimirovna
Scholastic degree
•
Academic rank
—
Honorary rank
—
Organization, job position
Kuban State University
Web site url
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Articles count: 51
In the article we have derived mathematical models of non-stationary transport binary electrolyte in EMS (electromembrane systems: electrodialysis apparatus, electromembrane cell, etc.) for the galvanostatic mode. To be specific, as EMS viewed channel of desalting of EDA (electrodialysis apparatus) and EMS with RMD (rotating membrane disk). We present a formula expressing the intensity of the electric field through the current density and concentration. Also, we have received the differential equation for the current density. The fundamental point here is derived new equation for the unknown vector function of current density of the initial system of equations of Nernst-Planck. In addition, the article shows the output equation for the current density in three dimensions; we have proposed various methods for solving the equation of the current density and the boundary conditions for the current density. The proposed mathematical models of transport binary electrolyte are easy to be generalized to an arbitrary electrolyte. However, the corresponding equations are cumbersome. It should be also noted that the boundary conditions can be varied and depend on the purpose of a particular study in this regard, in this work are just the equation having the general form
For effective management of economic and financial activity of a modern enterprise it is required to have information – software supply for its separate components: branches, divisions, services. Automation of the account allows accelerating significantly the process of granting, processing and the analysis of information necessary for the purposes of management. An important aspect on introduction of a program complex is the concept on its realization, i.e. the head of the company should define the way of development of automation of business - processes, what type of introduction is more preferable to the enterprise, what documents will formalize each of the stages. The article generalizes the data obtained by practical consideration on the basis of the realized projects on introduction of the automated systems in the companies from various fields of activity. The main stages of the design direction in the sphere of automation of business – processes are presented in this work, as well as the features of the subject and the characteristics of each stage, documentary objects for realization of each of them. Also on the basis of the carried-out analysis, the authors described a number of the existing shortcomings on realization of the design direction. In view of the data specified in article, the companies will be able to begin the project on automation of their own business effectively and quickly
The article presents a new approach to 2D modeling of transport of salt ions in EMC (electro systems: electrodialysis devices, electro-cells, etc.) under the condition of electrical neutrality with limiting and overlimiting current density. For definiteness as seen half of EMS channel EDA desalting (electrodialysis apparatus), the right border, which serves as a CEM (cation exchange membrane). The new approach in the use of partial differential equations of the first order, instead of equations of convective diffusion. A common method of transport modeling binary electrolyte in the EMS under the condition of electrical neutrality, is to use the equation of convective diffusion (partial differential equations of the second order). The article presents a new approach to modeling 2D transfer binary electrolyte in EMS under the same conditions, using partial differential equation of the first order for the decision, which does not require a boundary condition for concentration on the membrane surface. This allows you to simulate the transport of salt ions, as in prelimit and exorbitant current density and to determine the boundaries of the field of electrical neutrality
The modern Russian companies have realized the need of automation of document flow not only as a mean of keeping documents in order, but also as a tool of optimization of expenses, as an assistant in adoption of administrative decisions. The Russian market of information systems for long time had no software products intended for educational institutions. The majority of the automated systems are intended for the enterprises with an activity in the sphere of trade and production. In comparison with the above companies, the list of software products for commercial training centers is small. Even considering the developed line of programs it is impossible to speak about meeting all the requirements for companies of such activity. At creation of the automated system for training center, the analysis of the existing software products intended for automation of training centers and adjacent institutes was carried out; a number of features of activity are revealed. The article is devoted to the description of the developed automated information system of document flow of a commercial educational institution, namely the developed configuration of "Training center" on a platform of "1C: Enterprise 8.2". The developed program complex serving as the administrative tool for the analysis of economic activity of training center, scheduling of the educational equipment and teaching structure, payroll calculation taking into account specifics of branch has been presented in the article
Micro and nanofluidics are the new multidisciplinary
sciences. One of the tasks of which is creation and
management of flow of fluid in the thin channels size
of a few nano- or micrometer which exposed the
external electric field, where the walls are the ion
exchange membrane. Electroosmosis
(electroconvection) plays an important role in these
tasks. A large number of articless were devoted to
electroosmosis. One of the first, Dukhin S.S.,
Mishchuk N.A. and Rubinstein I. gave a theoretical
explanation of the overlimiting current by
electroosmosis. They used two-dimensional Stokes
equation to calculate the flow of the electrolyte, and
one-dimensional equations of Nernst-Planck and
Poisson to calculate the electric power. These
researches have multiple limitations because of the
computational complexity the mathematical
simulation. Thus, there is an actual problem of the
asymptotic solution of boundary value problems for
the two-dimensional systems of equations of NernstPlanck
and Poisson without these restrictions. These
researches we derived in simplified models of
electroosmosis in galvanic dynamical mode using the
decomposition method. We have created a hierarchical
system of two-dimensional mathematical models of
ion transport of salt and electroosmosis in micro- and
nanochannels formed by selective ion-exchange
membranes
This article describes a mathematical model of transport
of salt ions in a cell with a rotating disk cation exchange
membrane at transcendent current regimes, taking into
account electroconvection. Based on this model, we had
a theoretically study of the process of transfer of salt
ions and the dependence of the thickness of the
diffusion layer from the fall of potential. This article is
a continuation of [8] and [9], it conducted a numerical
analysis of boundary value problem for a system of
equations Nernst-Planck-Poisson and Navier-Stokes
equations, modeling the transport of salt ions in a
cylindrical cell with a rotating disc cation exchange
membrane based on electroconvection. It is shown there
is an electroconvection vortex in the center of the
membrane disc. The solution flows around this vortex
and forms a stagnation zone in front of it. With the
increase in the size of the fall of potential, the
electroconvective vortex decreases and at some value,
the electroconvective vortex disappears. The study was
conducted in the 1000 s when the angular velocity of 30 turns in a minute and change of the potential difference
of 0.2V to 1.4V with a step 0.1. As a result, in this
study it is shown that the thickness of the diffusion
layer is practically linearly dependent on the fall of
potential. The linear dependence of the thickness of
diffusion layer from the fall of potential, in the first
approximation, is disturbed by a slight deflection curve,
the causes of which are needed to be found by means of
extra experiments
This work presents a new approach to the countries’
credit rating definition, based on the advanced mathematical
models, such as neural network model, multiple
regression, cluster analysis and discriminant analysis.
A range of the analyses such as discriminant, cluster,
multiple regression models and a neural network
were performed on the following economic figures:
GDP per capita, GDP value, annual growth rate of
GDP, FDI - foreign investment, rate of unemployment,
consumer price inflation index, the size of government
debt in percentage of GDP. The results, obtained for
each model were combined in the countries’ credit
rating estimation system called "7M"
The influence of dissociation / recombination of water
molecules is important for understanding
electroconvection processes, as some authors believe
that the emergence of new carriers + H and − OH , and
can lead to a reduction in the space-charge and,
consequently, to electroconvection disappearance.
However, as shown in [5], the dissociation of water
molecules, although it reduces the space charge and
increases the threshold fall potential jump at which
begins electroconvection, yet it persists and effectively
mixes the solution. This article is devoted to
mathematical modeling of electrodiffusion of four
types of ions at the same time (two salt ions as well as
+ H and − OH ions) in the diffusion layer in electromembrane
systems with perfectly selective membrane
under the joint influence of violation of electrical neutrality, and the reaction of dissociation /
recombination of water molecules, development of
mathematical models of these processes, building
efficient algorithms asymptotic and numerical analysis
for different types of electrolytes. The work proposes a
new mathematical model of the process of transfer of
salt ions in view of the space charge and the
dissociation / recombination of water in the form of a
boundary value problem for a system of ordinary
differential equations. This system is reduced to a form
convenient for numerical solution. We have calculated
the required additional boundary conditions for the
electric field. Numerical and asymptotic solution of the
boundary value problem and physico-chemical
analysis of the influence of dissociation /
recombination on the transfer of salt ions is expected
to devote the next part of the work
This article is devoted to the asymptotic analysis of
boundary value problem for a system of equations of
Nernst-Planck and Poisson for a singularly perturbed
system of ordinary differential equations [1], based on
two parameters. This boundary value problem
simulates electrodiffusion of four kinds of ions at the
same time in the diffusion layer in electro-membrane
systems with perfectly selective membrane, taling into
consideration the reaction of recombination of two
ions. Meanwhile the other two ions represent ions of a
binary salt. As a simple example, we consider the
transport of ions sodium, chlorine, hydrogen and
hydroxide, moreover, hydrogen and hydroxyl ions
recombine in the diffusion layer. A more complex case
is the transfer of the products of dissociation of the
dihydrogen phosphate of sodium, namely, ions of
sodium and dihydrogen phosphate, the latter dissociate at the interface, in turn, hydrogen ions and hydrogen
phosphate. Thus, in the solution can simultaneously
store three different types of ions: sodium, hydrogen,
phosphate. During the transfer, hydrogen ions and ions
of hydrogen phosphate recombine to produce
phosphoric acid. The article has revealed the structure
of the Nernst diffusion layer at currents above
Harkatsa current. It is shown, that in the diffusion
layer, there are two types of boundary layers: the inner
(reaction) boundary layer and boundary layer at the
interface solution / membrane
This article focuses on the mathematical modeling of
evaluation of financial and economic activities of a
company and on definition (based on this model) of
such balance settings (line F1 and F2) which would
make financial-economic indicators of the activities of
the organization optimal, and the total cumulative
score was the maximum. The knowledge and the use
of the optimal parameters of the balance will allow the
managers to plan strategy for the future development
of the company. The article analyzes the dependencies
of each of the 15 basic indicators (profitability,
turnover, financial stability, liquidity and solvency) of
financial and economic activity of the organization on
the balance parameters. The optimal values of the
parameters of the balance and the main indicators of
financial and economic activities of the organization
have been found. We have also built a mathematical
model of optimal control of financial and economic
indicators in the form of a problem of mathematical
programming. For example, for the company called "Nika" it is shown the possibility of improving
estimation of financial and economic condition of the
organization. Knowledge of the optimal parameters of
the balance will allow the managers to plan strategy
for the future development of the organization. To
solve this problem we have used the method of
generalized reduced gradient implemented in Excel,
with which there was found a maximum of the
objective function for the article restrictions. The
article describes the analysis algorithm of the
optimization problem. A common assessment was
carried out in stages, based on the calculation
algorithm of sequentially improved target functions